oo7bob
+1y
When those two marks line up, the number one piston is at the top of its stroke. The 6 degrees before top dead center is when the distributor fires the number one plug, it sparks before the piston reaches the top so the explosion peaks when the piston is travelling back down.
The only way to set the timing is with the vehicle running, and a timing light. The distributor is rotated and you can adjust the timing closer or further from top dead center. If you have never broke the distributor loose, its probably right on.